4-乙酰氨基苯硫酚
外观
4-乙酰氨基苯硫酚 | |
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识别 | |
CAS号 | 1126-81-4 |
SMILES |
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性质 | |
化学式 | C8H9NOS |
摩尔质量 | 167.23 g·mol−1 |
熔点 | 155-156 °C[1] 153-154 °C(分解)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
4-乙酰氨基苯硫酚是一种有机硫化合物,化学式为C8H9NOS。它可由4-氨基苯硫酚和乙酸或乙酸酐反应制得。[3][4]它在硝酸铋催化下可以被氧气氧化为相应的二硫化物。[5]
参考文献
[编辑]- ^ Haikou, Maria N.; Ioannou, Panayiotis V. (2006). The Autoxidation of Triaryl Trithioarsenites, (ArS)3As: Evidence for Binding and Activation of Triplet Dioxygen by Arsenic(III). Phosphorus, Sulfur, and Silicon and the Related Elements, 181(2), 363–376. doi:10.1080/104265091000589
- ^ Gabel, Yu. O.; Shpanion, A. L. Synthesis of sulfur-containing chemotherapeutic preparations. II. 4-Nitro-4'-acetylaminodiphenyl sulfide. Zhurnal Prikladnoi Khimii. 1939, 12: 1485–1489. ISSN 0044-4618.
- ^ Wu, Bian-Peng; et al. Synthesis, fine structure of 19F NMR and fluorescence of novel amorphous TPA derivatives having perfluorinated cyclopentenyl and benzo[b]thiophene unit. Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (2013), 107, 39-45. doi:10.1016/j.saa.2013.01.019.
- ^ Shen, Jiaxuan; et al. Photocatalyst-free, metal-free, visible light-induced thiolation/pyridylation of styrenes using an electron donor-acceptor complex as a bifunctional reagent. Organic Chemistry Frontiers (2023), 10(5), 1166-1172. doi:10.1039/d2qo01889f.
- ^ Ioannou, Panayiotis V. Dioxygen activation by Bi(III) compounds: air oxidation of thiols to their disulfides. Main Group Chemistry (2013), 12(2), 125-138. doi:10.3233/MGC-130095.