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4-乙酰氨基苯硫酚

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4-乙酰氨基苯硫酚
识别
CAS号 1126-81-4  checkY
SMILES
 
  • O=C(NC1=CC=C(S)C=C1)C
性质
化学式 C8H9NOS
摩尔质量 167.23 g·mol−1
熔点 155-156 °C[1]
153-154 °C(分解)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

4-乙酰氨基苯硫酚是一种有机硫化合物,化学式为C8H9NOS。它可由4-氨基苯硫酚乙酸乙酸酐反应制得。[3][4]它在硝酸铋催化下可以被氧气氧化为相应的二硫化物。[5]

参考文献

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  1. ^ Haikou, Maria N.; Ioannou, Panayiotis V. (2006). The Autoxidation of Triaryl Trithioarsenites, (ArS)3As: Evidence for Binding and Activation of Triplet Dioxygen by Arsenic(III). Phosphorus, Sulfur, and Silicon and the Related Elements, 181(2), 363–376. doi:10.1080/104265091000589
  2. ^ Gabel, Yu. O.; Shpanion, A. L. Synthesis of sulfur-containing chemotherapeutic preparations. II. 4-Nitro-4'-acetylaminodiphenyl sulfide. Zhurnal Prikladnoi Khimii. 1939, 12: 1485–1489. ISSN 0044-4618. 
  3. ^ Wu, Bian-Peng; et al. Synthesis, fine structure of 19F NMR and fluorescence of novel amorphous TPA derivatives having perfluorinated cyclopentenyl and benzo[b]thiophene unit. Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (2013), 107, 39-45. doi:10.1016/j.saa.2013.01.019.
  4. ^ Shen, Jiaxuan; et al. Photocatalyst-free, metal-free, visible light-induced thiolation/pyridylation of styrenes using an electron donor-acceptor complex as a bifunctional reagent. Organic Chemistry Frontiers (2023), 10(5), 1166-1172. doi:10.1039/d2qo01889f.
  5. ^ Ioannou, Panayiotis V. Dioxygen activation by Bi(III) compounds: air oxidation of thiols to their disulfides. Main Group Chemistry (2013), 12(2), 125-138. doi:10.3233/MGC-130095.